Volume 294
Main Index

Issue 1, Pages 1-137 (8 October 1985)

A kinetic investigation of arene exchange and substitution in (naphthalene)Cr(CO)3 Pages c1-c4 James A. S. Howell, Denis T. Dixon, John C. Kola, Neil F. Ashford

Catalysis, science and technology, Vol. 6 : Edited by J.R. Anderson and M. Boudart, Springer-Verlag, Berlin, Heidelberg, 1984, ISBN 3-540-12815-8, pp. 312 + viii, DM 132. Page c15 G. J. Leigh

Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates Pages c5-c8 Lajos Bencze, László Prókai

Basic organometallic chemistry : By I. Haiduc and J.J. Zuckerman. W. de Gruyter, Berlin/New York, 1985. Paperback edition, xvi + 376 pages, DM 79, US$ 29.90. Hardcover, xvi + 486 pages, DM 169, US$ 64.90. ISBN 3-11-007184-3, ISBN 0-89925-006-8 Page c14 Alwyn G. Davies

Preliminary communicationÜbergangsmetall-thioketen-komplexe : XI. Synthese und struktur von bis(cyclopentadienyl)- (thioketen)niob-komplexen Pages c9-c13 Karsten Seitz, Ulrich Behrens

Author index Page c16

Organoboron compounds : XXVIII. Novel heterocyclic organoboranes Pages 1-6 R. Harry Cragg, Tim J. Miller

Contributions to group IV organometallic chemistry : X. Organo-1,3,2-diazasilacycloalkanes Pages 7-22 R. Harry Cragg, Rob. D. Lane

The crystal and molecular structure of fluoro(hydroxy){tris(dimethylphenylsilyl)methyl}borane Pages 23-30 Jerry L. Atwood, Simon G. Bott, Colin Eaborn, Mohammed N. A. El-Kheli and, J. David Smith

Indenyl and fluorenyl transition metal complexes : XIII. Determination of geometric configuration of (9-substituted fluorenes)chromium tricarbonyl complexes by ASIS-effect in 1H NMR spectra Pages 31-44 N. A. Ustynyuk, L. N. Novikova, V. K. Bel'skii, Yu. F. Oprunenko, S. G. Malyugina, O. I. Trifonova and, Yu. A. Ustynyuk

Bimetallic activation of coordinated ligands. Reactions of the Lewis acid (η-C5H5)(CO)3Mo+ PF6− with organo-iron and -molybdenum η1-methoxymethyl and ethyl complexes Pages 45-58 James Markham, William Tolman, Kevin Menard and, Alan Cutler

Photochemistry of metal—metal bonded complexes : III. MLCT photolysis of (CO)5MM′(CO)3(α-diimine) (M, M′ = Mn, Re) in 2-Me-THF and THF at 293 K; Evidence of photocatalytic formation of [(Mn(CO)3(α-diimine)(P(n-Bu)3)]+ [M(CO)5] - upon photolysis in the presence of P(n-Bu)3 Pages 59-73 Maarten W. Kokkes, Wim G. J. De Lange, Derk J. Stufkens, Ad Oskam

Kinetik und mechanismus der reversiblen öffnung von metall—metall-bindungen am beispiel von Cp(CO)2MnFe2(CO)6PR Pages 75-89 Josef Schneider, Martin Minelli, Gottfried Huttner

“Atmende” cluster: Addition und eliminierung als elementarschritte der ligandensubstitution an (μ3-RP)Fe3(CO)10 Pages 91-116 Konrad Knoll, Gottfried Huttner, Laszlo Zsolnai, Ibrahim Jibril, Marek Wasiucionek

Polymer-supported 2,2′-dipyridylmethane: Synthesis and formation of transition metal complexes Pages 117-122 Björn Elman, Christina Moberg

ortho-metallation reactions of variously substituted methylpyridines, quinoline, isoquinoline, diazines and 2,2′-bipyridine, with [Ru3(CO)10(NCMe)2] Pages 123-129 Gary A. Foulds, Brian F.G. Johnson, Jack Lewis

Gas phase oxidative-addition reactions of alkyl radicals at complexed cobalt(II) centres Pages 131-137 G. W. Dillow, I. K. Gregor, M. Guilhaus

Issue 2, Pages 139-272 (15 October 1985)

Author index Page c28

Novel cyclic “ylide-carbene” complexes : I. Synthesis of 3-(dimethylphenylphosphorane)indolidin-2-ylidene complexes of platinum(II) derived from metal-coordinated phosphonium-substituted isocyanide ligands Pages c21-c25 Giacomo Facchin, Renzo Campostrini, Rino A. Michelin

Corrigendum and addendum Pages c27-c28

The chemistry of the liquid alkali metals : By C.C. Addison (Emeritus Professor, University of Nottingham, GB) Wiley Interscience, 1984, x + 330 pages, £39, ISBN 0 471 90508 9. Page c26 J. David Smith

Heterogeneous catalytic hydrogenation of alkenes and alkynes in the presence of coordination polymers of palladium(0;II) and platinum(0;II) Pages c17-c20 Irene Jaffe, Marcos Segal, Avi Efraty

Un anion β-acyle masque dans les reactions d'acylation: Le derive lithie du dioxolanne du levulate de trimethylsilyle Pages 139-144 Jean-Louis Moreau, René Couffignal

Ultrasonic irradiation in the synthesis of triethylborane from ethyl bromide via ethylaluminum sesquibromide Pages 145-149 Kou-Fu Liou, Paw-Hwa Yang, Yih-Tsung Lin

Electronic transitions of polysilanes and their photochemistry Pages 151-161 E. A. Halevi, G. Winkelhofer, M. Meisl, R. Janoschek

Conversions of [2-(4,5-dihydrofuryl)]-silanes and -germanes under catalytic hydrogenation conditions Pages 163-171 E. Lukevics, V. N. Gevorgyan, Y. S. Goldberg, M. V. Shymanska

The molecular and electronic structure of radical cations derived from tetramethyltin and hexamethylditin: An SCF-MO study Pages 173-178 Christopher Glidewell

An 17O NMR study of some di- and tri-n-butyltin(IV) carboxylates Pages 179-182 A. Lyka, J. Holeek

Addition von phosphino- und arsino-substituierten schwefeldiimiden an H2Os3(CO)10: Kristallstruktur und dynamische struktureffekte von H2Os3(CO)10(tBu2PNSNAstBu2). Fragmentierung des NSN-gerüstes in H2Os3(CO)10(tBu2PNSNPtBu2) Pages 183-198 W. Ehrenreich, M. Herberhold, G. Herrmann, G. Süss-Fink, A. Gieren and, T. Hübner

Übergangsmetallkomplexe mit schwefelliganden , : XIV. (NEt4)2[Cr(CO)3(S2C6H4)], bis-tetraethylammoniumtricarbonyl-1,2-benzendithiolatochromat(0), ein 16e-konfigurierter chrom(0)-komplex mit fünffach koordiniertem chrom; röntgenstrukturanalyse und reaktionen Pages 199-207 Dieter Sellmann, Wolfgang Ludwig, Gottfried Huttner and, Laslo Zsolnai

Syntheses and reactions of [η5-CH3C5H4Cr(CO)3]2 Pages 209-212 R. M. Medina, A. Alvarez-Valdés, J. R. Masaguer

Carbon monoxide insertion reactions in substituted cyclopentadienylmolybdenum complexes Pages 213-217 J. D. Cotton, H. A. Kimlin

Reactions of coordinated cyclic polyolefins. A kinetic study of the pericyclic [3,3]-sigmahaptotropic rearrangement Pages 219-233 Zeev Goldschmidt, Hugo E. Gottlieb, Drora Cohen

Alkenyliron complexes. Cycloaddition reactions of organoiron metalloalkadienes Pages 235-250 Paul S. Waterman, John E. Belmonte, Thomas E. Bauch, Patricia A. Belmonte, Warren P. Giering

Synthesen im system {carbonylmetallat/ketenimin/säure} : XXX. Neue ferra- und rhenaazetidine Pages 251-260 Wolf Peter Fehlhammer, Peter Hirschmann, Alfons Völkl

Zur reaktivität komplexgebundener carbocyclen : XV. Neue wege zu indenyl-diolefen-komplexen von cobalt und rhodium Pages 261-266 A. Salzer, C. Täschler

Syntheses of mixed transition metal clusters containing the coordinated phosphaalkyne tBuCP Pages 267-272 Rainer Bartsch, John F. Nixon, Nigel Sarjudeen

Issue 3, Pages 273-396 (23 October 1985)

Stabilisation of highly substituted alkene coordination by chelation: Preparation and crystal and molecular structure of [Rh(Ph2PO2CC(H)=CMe2)Cl]2 Pages c29-c32 Domenico C. Cupertino, Marjorie M. Harding, David J. Cole-Hamilton

Author index Page c48

A new preparation of hexaalkylditins. 119Sn NMR and chromatographic data on linear polytins Pages c41-c45 Bernard Jousseaume, Evelyne Chanson, Marcel Bevilacqua, Annie Saux, Michel Pereyre, Bernard Barbe and, Michel Petraud

Subject index Pages c49-c53

Mehrfachbindungen zwischen hauptgruppenelementen und übergangsmetallen : XXII. Neue synthesebausteine in der organorheniumchemie: Substitutionsreaktionen an trioxo(η5-pentamethylcyclopentadienyl)rhenium(VII) Pages c37-c40 Wolfgang A. Herrmann, Erdmuthe Voss, Ulrich Küsthardt, Eberhardt Herdtweck

Mehrfachbindungen zwischen hauptgruppenelementen und übergangsmetallen : XXI. Zur oxophilie höhervalenter organorheniumfragmente: Synthese und molekülstruktur neuartiger (η5-C5Me5)ReO3- und (η5-C5Me5)ReO4-komplexe Pages c33-c36 Wolfgang A. Herrmann, Ulrich Küsthardt, Eberhardt Herdtweck

Advances in Organometallic Chemistry, Volume 23 : Edited by F.G.A. Stone and R. West, Academic Press, Inc., Orlando, San Diego, New York, London, Toronto, Montreal, Sydney, Tokyo, 1984, viii + 324 pages, US $65. ISBN 0-12-031123-2. Pages c46-c47 Elaine A. Seddon, Kenneth R. Seddon

Stickstoffverbindungen von elementen der dritten hauptgruppe mit intra- und intermolekularen donor—akzeptor-bindungen : II. Strukturelle untersuchungen Pages 273-294 M. Veith, H. Lange, O. Recktenwald, W. Frank

Radikalionen : LXVIII. Cyclovoltammetrische messungen an organosilizium-substituierten π-systemen: Abschätzung des oxidationspotentials für das einelektronentransfer-system AlCl2/H2CCl2 Pages 295-304 Hans Bock, Ulrike Lechner-Knoblauch

Some tetrasilylmethane derivatives Pages 305-313 Colin Eaborn, Paul D. Lickiss

Synthesis and configurations of 2-methyl-1-organo-1-halo-1-telluracyclopentanes Pages 315-319 Ali Z. Al-Rubaie, Hatif A. Al-Shirayda

Ligand redistribution reactions of dicyclopentadienylzirconium(IV) complexes Pages 321-326 Richard F. Jordan

Reaction of molybdenum—molybdenum triple bonded compounds with group VIII peroxo-transition metal complexes Pages 327-331 Henri Arzoumanian, André Baldy, Marcel Pierrot, Jean-François Petrignani

Übergangsmetallkomplexe mit schwefelliganden : XV. Thioether-desalkylierungs- und redoxreaktionen bei der koordination von vierzähnigen thioether-thiolat-liganden an molybdän(II)-zentren; Synthese von komplexen des typs [Mo(CO)x(PMe3)y(SC6H4S(CH2)nSC6H4S)], (x + y = 3, n = 1–4), [Mo(PMe3)2(SC6H4S(CH2)3SC6H4S)] sowie [Mo(CO)3(PMe3)2(S2C6H4)] und [Mo(PMe3)2(S2C6H4)2] Pages 333-346 Dieter Sellmann, Wolfgang Reisser

Metallophosphoranes: Carbonyl substitution reactions and the X-ray crystal structure of cis-Cat2PMn(CO)4P(OPh)3 (Cat = benzodioxyl) Pages 347-355 Suman K. Chopra, Shirley S. C. Chu, Patrice De Meester, Darren E. Geyer, Michael Lattman, Scott A. Morse

Ruthenium-catalysed rearrangements of azobenzenes : I. The preparation of 1-phenylbenzimidazoles from azobenzene derivatives and tertiary amines catalysed by ruthenium complexes Pages 357-366 Alwyn Spencer

Structural studies on polynuclear osmium carbonyl hydrides : XXXII. Crystal and molecular structure of CpWOs3(CO)9(μ-H)(μ-O)[μ-C=CH(p-tol)], a hydrido-vinylidene cluster complex produced by rearrangement of a μ3-alkylidyne cluster Pages 367-377 Melvyn Rowen Churchill, Yong-Ji Li

Electrochemistry of coordination compounds : XXII. Electrogeneration and characterization of monomeric iridium(II) organometallic complexes [Ir(R)(CO)(PPh3)3]+ Pages 379-388 Sandro Zecchin, Gianni Zotti, Giuseppe Pilloni

Mono- and di-cycloplatinated derivatives of benzalazines Pages 389-396 Rosa Maria Ceder, Joaquim Sales